Volkswagen Touran Service Manual: Refrigerant R134a Characteristics
Commercial Names and Designations
Refrigerant R134a is currently available under the following
trade names: |
Note
Different trade names may be used in other countries. |
Of the wide range of refrigerants available, this is the
only one which may be used for vehicles. The designations Frigen
and Freon are trade names. They also apply to refrigerants which
may not be used in automotive vehicles. |
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Color
Like water, refrigerants are colorless in both vapor and
liquid form. Gas is invisible. Only the boundary layer between
gas and liquid is visible. (Liquid level in tube of charging
cylinder or bubbles in sight glass). Refrigerant R134a fluid may
appear colored (milky) in a sight glass. This cloudiness is
caused by partially dissolved refrigerant oil and does not
indicate a malfunction. |
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Vapor Pressure
In a partially filled, closed vessel, the quantity of
refrigerant evaporating from the surface equals the quantity
returning to the liquid state as vapor particles condense. This
state of equilibrium occurs under the influence of pressure and
is often called vapor pressure. Vapor pressure is dependent on
temperature. Refer to
→ Chapter "Refrigerant R134a Vapor Pressure Table". |
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R134a Physical Characteristics
The vapor pressure curves of R134a and other refrigerants
are sometimes very similar, therefore it is not possible to make
a certain distinction solely by pressure. |
With R134a, the A/C compressor is lubricated with special
synthetic refrigerant oils, for example. PAG oils (polyalkylene
glycol oils). |
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Affect on Metal
In its pure state, refrigerant R134a is chemically stable
and does not corrode iron or aluminum. |
Refrigerant impurities such as chlorine compounds however
cause corrosion of certain metals and plastics. This can lead to
blockage, leaks or deposits on the A/C compressor piston. |
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Critical Temperature/Pressure
The refrigerant R134a remains chemically stable up to a gas
pressure of 39.5 bar (572.9 psi) (corresponding to a temperature
of 101 C (213 F). Above this temperature, the refrigerant
decomposes. Refer to
→ Chapter "Combustibility". |
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Water Content
Only very small amounts of water are soluble in liquid
refrigerant. On the other hand, refrigerant vapor and water
vapor mix in any ratio. |
Only a small drop of water may get into the refrigerant
circuit. The dryer, dryer bag or dryer cartridge contained in
the reservoir can absorb approximately 7 grams of water. They
are then saturated and cannot absorb any more water. If water is
still present in the refrigerant circuit, it flows up to the
expansion valve nozzle or restrictor and becomes ice. |
The air conditioning system stops cooling. |
Water destroys the air conditioner as it combines with other
impurities at high pressures and temperatures to form acids. |
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Combustibility
Refrigerant is non-flammable. It actually has a fire
resistant or fire extinguishing effect. Refrigerant decomposes
when exposed to flames or red-hot surfaces. UV light (occurring
for example during electric welding) also causes refrigerant
decomposition. The resultant decomposition products are toxic
and are not to be inhaled. However, irritation of the mucous
membranes provides an adequate and timely warning. |
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A vessel must have space for vapor as well as liquid. As the
temperature rises, the liquid expands. The space filled with
vapor decreases. At a certain point, there will only be liquid
in the vessel. Beyond this, even a slight increase in
temperature causes high pressure to build up in the vessel as
the liquid tries to continue expanding even though there is not
enough space for it. The forces that result are strong enough to
rupture the vessel. To prevent a vessel from being overfilled,
the regulations regarding compressed gasses specify how many
kilograms of refrigerant that may be added to a vessel per liter
of interior volume. The product of multiplying this charge
factor by the internal volume of the vessel is the permissible
capacity. The figure for refrigerant used in vehicles is 1.15
kg/liter. |
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Evidence of Leaks
External damage, for example, can cause a leak in the
refrigerant circuit. The small quantity of refrigerant escaping
from minor leaks can be detected for example using an electronic
leak detector or by introducing a leak detection additive into
the refrigerant circuit. Electronic leak detectors are capable
of registering leaks with refrigerant losses of less than 5 g
per year. Use leak detectors designed for the type of
refrigerant. For example, a leak detector for R12 refrigerant
will not work with R134a because R134a refrigerant has no
chlorine atoms so the leak detector will not respond to it. |
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Refrigerant R134a Physical Data
Vehicle air conditioning systems make use of the
vaporization and condensation process. In this case, one works
with a substance whic ...
Refrigerant oil mixes with the refrigerant (about 20 - 40%,
depending on compressor type and amount of refrigerant) and
circulates constantly in the system, lubricati ...
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